Dissecting the packing forces in mixed perfluorocarbon/aromatic co-crystals

Author:

Saccone Marco1ORCID,Pace Andrea2ORCID,Pibiri Ivana2ORCID,Cavallo Gabriella3,Metrangolo Pierangelo3ORCID,Pilati Tullio3,Resnati Giuseppe3ORCID,Terraneo Giancarlo3ORCID

Affiliation:

1. Dipartimento di Ingegneria, Università Degli Studi di Palermo, Viale Delle Scienze, Edificio 6, 90128, Palermo, Italy

2. Dipartimento di Scienze e Tecnologie Biologiche Chimiche e Farmaceutiche – STEBICEF, Università Degli Studi di Palermo, Viale Delle Scienze, Edificio 17, 90128, Palermo, Italy

3. Dipartimento di Chimica, Materiali e Ingegneria Chimica DCMIC, Politecnico di Milano, Via Mancinelli 7, 20131 Milano, Italy

Abstract

The nature and role of non-covalent interactions involving fluorous molecules and aromatic molecules are studied by a combined theoretical/crystallographic approach.

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Reference58 articles.

1. G. R.Desiraju , J. J.Vittal and A.Ramanan , Crystal Engineering: A Textbook , World Scientific , Singapore , 2011

2. A. I.Kitaigorodsky , Molecular Crystals and Molecules , Academic Press , New York , 1973

3. J. J.Novoa , Intermolecular Interactions in Crystals: Fundamentals of Crystal Engineering , The Royal Society of Chemistry , London , 2018

4. I. T.Horváth , D. P.Curran and J. A.Gladysz , in Handbook of Fluorous Chemistry , ed. J. A. Gladysz , D. P. Curran and I. T. Horváth , Wiley-VCH Verlag GmbH & Co. KGaA , Weinheim , 2004 , ch. 1, pp. 1–4

5. Understanding organofluorine chemistry. An introduction to the C–F bond

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