Ligand-free Guerbet-type reactions in air catalyzed by <i>in situ</i> formed complexes of base metal salt cobaltous chloride-Reference-Cited by-同舟云学术

Ligand-free Guerbet-type reactions in air catalyzed by in situ formed complexes of base metal salt cobaltous chloride

Published:2022 Issue:4 Volume:12 Page:1100-1108
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Nandi Pran Gobinda¹,Kumar Pradhuman¹,Kumar Akshai¹²³^ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati, 781039, Assam, India

2. Centre for Nanotechnology, Indian Institute of Technology Guwahati, Guwahati, 781039, Assam, India

3. School of Health Science & Technology, Indian Institute of Technology Guwahati, Guwahati, 781039, Assam, India

Abstract

Inexpensive, earth-abundant & environmentally benign CoCl2 efficiently catalyses the β-alkylation of alcohol in unprecedented yields (89%) & turnovers (8900). Mechanistic studies are indicative of in situ generated homogeneous molecular Co catalysts.

Funder

Ministry of Human Resource Development

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CY/D1CY02159A

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1. Stereoselective Synthesis of Cyclohexanes via an Iridium Catalyzed (5 + 1) Annulation Strategy

2. Recent Advances in Radical C–H Activation/Radical Cross-Coupling