Inorganic–organic hybrid Cu–dipyridyl semiconducting polymers based on the redox-active cluster [SFe3(CO)9]2−: filling the gap in iron carbonyl chalcogenide polymers

Author:

Hsu Ming-Chi1,Lin Ru Yan1,Sun Tzu-Yen1,Huang Yu-Xin1,Li Min-Sian1,Li Yu-Huei1,Chen Hui-Lung2,Shieh Minghuey1ORCID

Affiliation:

1. Department of Chemistry, National Taiwan Normal University, Taipei 116325, Taiwan, Republic of China

2. Department of Chemistry and Institute of Applied Chemistry, Chinese Culture University, Taipei 111396, Taiwan, Republic of China

Abstract

SFe3(CO)9-based Cu–dipyridyl polymers were synthesized by LAG, where their structures/bonding modes/transformations, semiconducting and redox-active behaviors, and electron transport were demonstrated.

Funder

National Science and Technology Council

Publisher

Royal Society of Chemistry (RSC)

Reference65 articles.

1. S. R.Batten , S. M.Neville and D. R.Turner , Coordination polymers: design, analysis and application , Royal Society of Chemistry , 2008

2. J. W.Steed and J. L.Atwood , Supramolecular chemistry , John Wiley & Sons , 2022

3. Heavy chalcogenide-transition metal clusters as coordination polymer nodes

4. Entangled Two-Dimensional Coordination Networks: A General Survey

5. The Chemistry and Applications of Metal-Organic Frameworks

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