Chemoselective and diastereodivergent synthesis of new spirooxindolo-pyrrolizidines and pyrrolidines stemming from unsymmetrical 1,3-bis(arylidene)tetral-2-ones: a combined experimental and theoretical study-Reference-Cited by-同舟云学术

Chemoselective and diastereodivergent synthesis of new spirooxindolo-pyrrolizidines and pyrrolidines stemming from unsymmetrical 1,3-bis(arylidene)tetral-2-ones: a combined experimental and theoretical study

Published:2022 Issue:40 Volume:46 Page:19198-19212
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Gazzeh Houda¹,Rouatbi Fadwa¹,Chniti Sami¹,Askri Moheddine¹^ORCID,Knorr Michael²^ORCID,Strohmann Carsten³,Golz Christopher⁴,Lamsabhi Al Mokhtar⁵⁶^ORCID

Affiliation:

1. Laboratory of Heterocyclic Chemistry Natural Product and Reactivity/CHPNR, Department of Chemistry, Faculty of Science of Monastir, 5000 Monastir, Tunisia

2. Institute UTINAM-UMR CNRS 6213, Université de Franche-Comté, 16 Route de Gray, 25030 Besançon, France

3. Technische Universität Dortmund, Anorganische Chemie Otto-Hahn-Strasse 6, 44221 Dortmund, Germany

4. Georg-August-University Göttingen, Institute of Organic and Biomolecular Chemistry, Tammann-Straße 2, D-37077, Göttingen, Germany

5. Department of Chemistry, Universidad Autónoma de Madrid, Cantoblanco, 28049 Madri, Spain

6. Institute for Advanced Research in Chemical Sciences (IAdChem), Universidad Autónoma de Madrid, 28049 Madrid, Spain

Abstract

An experimental and theoretical study of an efficient one-pot three-components cycloaddition reaction leading to pentacyclic dispiropyrrolizidin/pyrrolidinoxindoles endowed by four contiguous stereogenic centres with moderate to good yields was reported.

Funder

Consejería de Educación e Investigación

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NJ/D2NJ03887K

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3. Chemical ecology of pyrrolizidine alkaloids

4. 5-Substituted-furan-2(3H)-ones in [8 + 2]-Cycloaddition with 8,8-Dicyanoheptafulvene

5. Catalytic cycloaddition of CO2 to epoxides by the synergistic effect of acidity and alkalinity in a functionalized biochar

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