Gel-to-gel non-variant transition of an organogel caused by polymorphism from nanotubes to crystallites

Author:

Schwaller Duncan123,Zapién-Castillo Samuel456ORCID,Carvalho Alain123,Combet Jérôme123,Collin Dominique123,Jacomine Leandro123,Kékicheff Patrick123ORCID,Heinrich Benoît783ORCID,Lamps Jean-Philippe123,Díaz-Zavala Nancy P.456,Mésini Philippe J.123910ORCID

Affiliation:

1. Université de Strasbourg, CNRS, Institut Charles Sadron

2. F-67000 Strasbourg

3. France

4. Tecnológico Nacional de México-Instituto Tecnológico de Ciudad Madero, Centro de Investigación en Petroquímica. Prolongación Bahía de Aldair, Ave. de las Bahías

5. 89600 Altamira

6. Mexico

7. Institut de Physique et Chimie des Matériaux de Strasbourg (IPCMS), UMR 7504 CNRS-Université de Strasbourg

8. 67034 Strasbourg

9. International Center for Frontier Research in Chemistry

10. 67000 Strasbourg

Abstract

An organogel shows a gel-to-gel transition corresponding to the transformation of nanotubular aggregates into plain fibers, either by heating or aging. The domains of the existence of both gels are mapped in the cT phase diagram.

Funder

Consejo Nacional de Ciencia y Tecnología

Ministère de l'Enseignement Supérieur et de la Recherche

Tecnológico Nacional de México

Indo-French Centre for the Promotion of Advanced Research

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Chemistry

Reference35 articles.

1. M. George and R. G.Weiss , in Molecular Gels , ed. R. G. Weiss and P. Terech , Springer , Netherlands , 2006 , pp. 449–551

2. R. G. Weiss , Molecular Gels , The Royal Society of Chemistry , 2018

3. F. Fages , ed., Low Molecular Mass Gelators - Design, Self-Assembly, Function , Springer Berlin Heidelberg , Berlin, Heidelberg , 2005 , vol. 256

4. High-Tech Applications of Self-Assembling Supramolecular Nanostructured Gel-Phase Materials: From Regenerative Medicine to Electronic Devices

5. Supramolecular Hydrogelators and Hydrogels: From Soft Matter to Molecular Biomaterials

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