A Co(ii)-coordination polymer for ultrahigh superprotonic conduction: an atomistic insight through molecular simulations and QENS experiments

Author:

Pal Shyam Chand123,Chand Santanu123,Kumar Anaparthi Ganesh423,Mileo Paulo G. M.56789,Silverwood Ian1011121314ORCID,Maurin Guillaume56789ORCID,Banerjee Susanta423ORCID,Elahi Syed Meheboob123,Das Madhab C.123ORCID

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology Kharagpur

3. India

4. Materials Science Centre

5. ICGM

6. Univ. Montpellier

7. CNRS

8. ENSCM

9. Montpellier

10. Neutron and Muon Facility

11. Science and Technology Facilities Council

12. Rutherford Appleton Laboratory

13. Harwell Science and Innovation Campus

14. Oxon OX11 0QX

Abstract

A superprotonic conducting coordination polymer PCM-1 was synthesized. Joint experimental/modeling study revealed water-assisted proton dynamics through the formation of a long-range H-bonded network mediated by the Teixeira jump-diffusion model.

Funder

Council of Scientific and Industrial Research, India

Science and Technology Facilities Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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