Semiquinone radical-bridged M2 (M = Fe, Co, Ni) complexes with strong magnetic exchange giving rise to slow magnetic relaxation

Author:

Chakarawet Khetpakorn1234ORCID,Harris T. David1234ORCID,Long Jeffrey R.12345ORCID

Affiliation:

1. Department of Chemistry

2. University of California Berkeley

3. Berkeley

4. USA

5. Department of Chemical and Biomolecular Engineering

Abstract

A semiquinone radical bridging two trigonal bipyramidal metal centers facilitates strong magnetic exchange and single-molecule magnet behavior.

Funder

Office of Science

Division of Chemistry

National Institutes of Health

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference40 articles.

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2. Photosystem II: the light-drive water: plastoquinone oxidoreductase , ed. T. J. Wydrzynski and K. Satoh , Springer , 2006

3. Biochemical, physiological and medical aspects of ubiquinone function

4. The Structure and Ferrimagnetic Behavior of meso ‐Tetraphenyl‐ porphinatomanganese( III ) Tetrachloro‐1,4‐Benzoquinonide, [Mn III TPP] + [QCl 4 ] . − ⋅PhMe: Evidence of a Quinoidal Structure for [QCl 4 ] . −

5. Hydrogen-bonded networks from η5-semiquinone complexes of manganese tricarbonyl

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