Semiquinone radical-bridged M2 (M = Fe, Co, Ni) complexes with strong magnetic exchange giving rise to slow magnetic relaxation
Author:
Affiliation:
1. Department of Chemistry
2. University of California Berkeley
3. Berkeley
4. USA
5. Department of Chemical and Biomolecular Engineering
Abstract
A semiquinone radical bridging two trigonal bipyramidal metal centers facilitates strong magnetic exchange and single-molecule magnet behavior.
Funder
Office of Science
Division of Chemistry
National Institutes of Health
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC03078C
Reference40 articles.
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3. Biochemical, physiological and medical aspects of ubiquinone function
4. The Structure and Ferrimagnetic Behavior of meso ‐Tetraphenyl‐ porphinatomanganese( III ) Tetrachloro‐1,4‐Benzoquinonide, [Mn III TPP] + [QCl 4 ] . − ⋅PhMe: Evidence of a Quinoidal Structure for [QCl 4 ] . −
5. Hydrogen-bonded networks from η5-semiquinone complexes of manganese tricarbonyl
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