Anion-enhanced excited state charge separation in a spiro-locked N-heterocycle-fused push-pull zinc porphyrin-Reference-Cited by-同舟云学术

Anion-enhanced excited state charge separation in a spiro-locked N-heterocycle-fused push-pull zinc porphyrin

Published:2021 Issue:13 Volume:12 Page:4925-4930
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Chahal Mandeep K.¹²³⁴^ORCID,Liyanage Anuradha⁵⁶⁷⁸,Alsaleh Ajyal Z.⁵⁶⁷⁸,Karr Paul A.⁹¹⁰¹¹⁸,Hill Jonathan P.¹²³⁴^ORCID,D'Souza Francis⁵⁶⁷⁸^ORCID

Affiliation:

1. International Centre for Materials Nanoarchitectonics (WPI-MANA)

2. National Institute for Materials Science (NIMS)

3. Ibaraki

4. Japan

5. Department of Chemistry

6. University of North Texas

7. Denton

8. USA

9. Department of Physical Sciences and Mathematics

10. Wayne State College

11. Wayne

Abstract

A new type of push–pull charge transfer complex, viz., a spiro-locked N-heterocycle-fused zinc porphyrin, ZnP-SQ, is shown to undergo excited state charge separation, which is enhanced by axial F⁻ binding to the Zn center.

Funder

National Science Foundation

Ministry of Education, Culture, Sports, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC00038A

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