Kinetic investigation of the cyclopropanation process of fullerene C60 by halogenmethyl ketones under the conditions of the Bingel reaction
Author:
Affiliation:
1. Ufa Institute of Chemistry
2. Ufa Federal Research Centre
3. Russian Academy of Sciences
4. 450054 Ufa
5. Russian Federation
6. Institute of Mathematics
7. 450008 Ufa
Abstract
The kinetics of the Bingel reaction with halogenmethyl ketones and C60 fullerene has been studied in streaming mode by sampling the reaction mixture at different time intervals and separating the components using HPLC.
Funder
Ministry of Education and Science of the Russian Federation
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2020/NJ/C9NJ06326A
Reference40 articles.
1. Cyclopropanierung von Fullerenen
2. Nucleophilic cyclopropanation of [60]fullerene by the addition–elimination mechanism
3. Kinetic Study of the Diels–Alder Reaction of Li+@C60 with Cyclohexadiene: Greatly Increased Reaction Rate by Encapsulated Li+
4. Notably Enhanced Reactivity of the Fulleroid anti-Bredt Double Bond in Diels-Alder Reactions
5. First kinetic evidence for the CH/π and π/π solute–solvent interaction of C60 in the Diels–Alder reaction with cyclohexadiene
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1. Theoretical study on the stabilities, electronic structures, and reaction and formation mechanisms of fullerenes and endohedral metallofullerenes;Coordination Chemistry Reviews;2022-11
2. Bingel–Hirsch Addition of Diethyl Bromomalonate to Ion‐Encapsulated Fullerenes M@C 60 (M=Ø, Li + , Na + , K + , Mg 2+ , Ca 2+ , and Cl − );Chemistry – A European Journal;2020-10-06
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