A van der Waals DFT study of chain length dependence of alkanethiol adsorption on Au(111): physisorption vs. chemisorption-Reference-Cited by-同舟云学术

A van der Waals DFT study of chain length dependence of alkanethiol adsorption on Au(111): physisorption vs. chemisorption

Published:2017 Issue:21 Volume:19 Page:13756-13766
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Mete Ersen¹²³⁴^ORCID,Yortanlı Merve¹²³⁴,Danışman Mehmet Fatih⁵⁶⁷⁴

Affiliation:

1. Department of Physics

2. Balıkesir University

3. Balıkesir 10145

4. Turkey

5. Department of Chemistry

6. Middle East Technical University

7. Ankara 06800

Abstract

Coverage and size dependent chain–chain electronic interactions counteract with the alkyl chain–gold surface interactions and the surface relaxation of the metal in the formation of standing up monolayer structures.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CP/C7CP01653K

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5. Spontaneously organized molecular assemblies. 4. Structural characterization of n-alkyl thiol monolayers on gold by optical ellipsometry, infrared spectroscopy, and electrochemistry

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