Trapping an unusual pentacoordinate carbon atom in a neutral trialuminum complex-Reference-Cited by-同舟云学术

Trapping an unusual pentacoordinate carbon atom in a neutral trialuminum complex

Published:2021 Issue:80 Volume:57 Page:10327-10330
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Villegas-Escobar Nery¹^ORCID,Martínez Javier²^ORCID,Matute Ricardo A.¹³^ORCID,Saltarini Sebastián⁴,Daniliuc Constantin G.⁵^ORCID,Gade Lutz H.⁶,Rojas René S.⁴^ORCID

Affiliation:

1. Centro Integrativo de Biología y Química Aplicada (CIBQA), Universidad Bernardo O’Higgins, General Gana 1702, Santiago 8370854, Chile

2. Instituto de Ciencias Químicas, Facultad de Ciencias, Isla Teja, Universidad Austral de Chile, Valdivia 5090000, Chile

3. Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, USA

4. Laboratorio de Química Inorgánica, Facultad de Química y Farmacia, Pontificia Universidad Católica de Chile, Santiago 6094411, Chile

5. Organisch-Chemisches Institut der Universität Münster, Münster 48149, Germany

6. Anorganisch-Chemisches Institut, Universität Heidelberg, Im Neuenheimer Feld 270, Heidelberg 69120, Germany

Abstract

A pentacoordinate methylidene carbon atom was trapped in a neutral trimetallic aluminum core using a naphthalene bis amidinate ligand. The resulting complex exhibits the shortest equatorial Al–C bond distance reported for Al3-(μ3-CH2) moieties.

Funder

Fondo Nacional de Desarrollo Científico y Tecnológico

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC04265C

Reference47 articles.

1. Synthesis and Isolation of Stable Hypervalent Carbon Compound (10-C-5) Bearing a 1,8-Dimethoxyanthracene Ligand

2. Synthesis and Characterization of Stable Hypervalent Carbon Compounds (10-C-5) Bearing a 2,6-Bis(p-substituted phenyloxymethyl)benzene Ligand

3. Syntheses and Structures of Hypervalent Pentacoordinate Carbon and Boron Compounds Bearing an Anthracene Skeleton − Elucidation of Hypervalent Interaction Based on X-ray Analysis and DFT Calculation

4. Synthesis and Structure of a Hexacoordinate Carbon Compound

5. C(CN)5–: transition state or intermediate?

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