Dehydrogenative oxidation of hydrosilanes using gold nanoparticle deposited on citric acid-modified fibrillated cellulose: unveiling the role of molecular oxygen

Author:

Suwattananuruk Butsaratip1,Uetake Yuta12ORCID,Ichikawa Rise3,Toyoshima Ryo3,Kondoh Hiroshi3ORCID,Sakurai Hidehiro12ORCID

Affiliation:

1. Division of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan

2. Innovative Catalysis Science Division, Institute for Open and Transdisciplinary Research Initiatives (ICS-OTRI), Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan

3. Department of Chemistry, Faculty of Science and Technology, Keio University, Kohoku-ku, Yokohama 223-8522, Japan

Abstract

We developed an efficient and environmentally friendly catalyst, Au:F-CAC, for the dehydrogenative oxidation of hydrosilanes. Detailed analyses revealed that the cationic Au sites generated via the adsorption of oxygen play an important role.

Funder

JST-Mirai Program

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Reference45 articles.

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