First investigation of polyoxoniobate and polyoxotantalate aqueous speciation by capillary zone electrophoresis

Author:

Deblonde Gauthier J.-P.12345,Delaunay Nathalie16789,Lee Dahye16789,Chagnes Alexandre12345,Cote Gérard12345,Gareil Pierre16789

Affiliation:

1. PSL Research University

2. Chimie ParisTech – CNRS

3. Institut de Recherche de Chimie Paris

4. 75005 Paris

5. France

6. ESPCI ParisTech

7. Laboratory of Analytical and Bioanalytical Sciences and Miniaturization

8. UMR CBI 8231

9. 75231 Paris Cedex 05

Abstract

Aqueous solutions of hexaniobate (HxNb6O19x−8, 0 ≤ x ≤ 3) and hexatantalate ions (HxTa6O19x−8, 0 ≤ x ≤ 3) have been probed by capillary zone electrophoresis (CE) for the first time.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference34 articles.

1. Roskill Information Services , The economics of niobium, Roskill Information Services, London, 2009

2. Niobium and tantalum: State of the world market, fields of application, and raw sources. Part I

3. Niobium and tantalum: State of the world market, application fields, and sources of raw materials. Part 2

4. A. Agulyanski , The chemistry of tantalum and niobium fluoride compounds, Elsevier, Amsterdam , Boston, 1st edn, 2004

5. Solvent extraction technology for the separation and purification of niobium and tantalum: A review

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