Structure sensitivity of alumina- and zeolite-supported platinum ammonia slip catalysts

Author:

Marchuk Vasyl1ORCID,Huang Xiaohui23,Grunwaldt Jan-Dierk14ORCID,Doronkin Dmitry E.14ORCID

Affiliation:

1. Institute for Chemical Technology and Polymer Chemistry (ITCP), Karlsruhe Institute of Technology, Engesserstr. 20, 76131, Karlsruhe, Germany

2. Institute of Nanotechnology (INT), Karlsruhe Institute of Technology, Hermann-von-Helmholtz-Platz 1, 76344, Eggenstein-Leopoldshafen, Germany

3. Department of Materials and Earth Sciences, Technische Universität Darmstadt, Alarich-Weiss-Straße 2, 64287, Darmstadt, Germany

4. Institute of Catalysis Research and Technology (IKFT), Karlsruhe Institute of Technology, Hermann-von-Helmholtz-Platz 1, 76344, Eggenstein-Leopoldshafen, Germany

Abstract

NH3 is effectively oxidised on Pt via O-activated dissociation when a minimum particle size to contain a favourable surface atom configuration is reached. Different mechanisms were found to govern NH3 oxidation on nanoparticles and single sites.

Funder

Helmholtz-Gemeinschaft

China Scholarship Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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