Highly dispersed Rh single atoms over graphitic carbon nitride as a robust catalyst for the hydroformylation reaction-Reference-Cited by-同舟云学术

Highly dispersed Rh single atoms over graphitic carbon nitride as a robust catalyst for the hydroformylation reaction

Published:2023 Issue:5 Volume:13 Page:1425-1436
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Jurado Lole¹^ORCID,Esvan Jerome²,Luque-Álvarez Ligia A.³^ORCID,Bobadilla Luis F.³^ORCID,Odriozola José A.³^ORCID,Posada-Pérez Sergio⁴,Poater Albert⁴^ORCID,Comas-Vives Aleix⁵⁶^ORCID,Axet M. Rosa¹^ORCID

Affiliation:

1. CNRS, LCC (Laboratoire de Chimie de Coordination), UPS, INPT, Université de Toulouse, 205 Route de Narbonne, F-31077 Toulouse Cedex 4, France

2. CIRIMAT, CNRS-INPT-UPS, Université de Toulouse, 4 Allée Emile Monso, 31030 Toulouse, France

3. Departamento de Química Inorgánica e Instituto de Ciencia de Materiales de Sevilla, Centro Mixto CSIC-Universidad de Sevilla, Av. Américo Vespucio 49, 41092 Sevilla, Spain

4. Institut de Química Computacional i Catàlisi and Departament de Química, Universitat de Girona, c/ Maria Aurèlia Capmany 69, 17003 Girona, Catalonia, Spain

5. Institute of Materials Chemistry, TU Wien, 1060 Vienna, Austria

6. Departament de Química, Universitat Autònoma de Barcelona, 08193 Cerdanyola del Vallès, Catalonia, Spain

Abstract

Rhodium single-atoms on carbon nitride are robust and efficient catalysts for the hydroformylation of styrene. Experimental analyses and DFT calculations confirm the isolated nature of the Rh atoms on carbon nitride and their robustness as catalysts.

Funder

European Social Fund

Ministerio de Ciencia e Innovación

Centre National de la Recherche Scientifique

Institució Catalana de Recerca i Estudis Avançats

Marie Curie

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CY/D2CY02094G