Photochemically triggered cheletropic formation of cyclopropenone (c-C<sub>3</sub>H<sub>2</sub>O) from carbon monoxide and electronically excited acetylene-Reference-Cited by-同舟云学术

Photochemically triggered cheletropic formation of cyclopropenone (c-C₃H₂O) from carbon monoxide and electronically excited acetylene

Published:2022 Issue:29 Volume:24 Page:17449-17461
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Wang Jia¹²,Kleimeier N. Fabian¹²^ORCID,Johnson Rebecca N.³,Gozem Samer³^ORCID,Abplanalp Matthew J.¹²,Turner Andrew M.¹²,Marks Joshua H.¹²,Kaiser Ralf I.¹²^ORCID

Affiliation:

1. Department of Chemistry, University of Hawaii at Manoa, Honolulu, HI 96822, USA

2. W. M. Keck Research Laboratory in Astrochemistry, University of Hawaii at Manoa, Honolulu, HI 96822, USA

3. Department of Chemistry, Georgia State University, Atlanta, GA 30302, USA

Abstract

Cyclopropenone is one of few organic molecules detected in interstellar molecular clouds to date. Its formation mechanism from carbon monoxide and photoexcited acetylene is investigated, giving key insight into its formation in extreme conditions.

Funder

Division of Chemistry

Division of Astronomical Sciences

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP01978G

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1. Conformer-specific polar cycloaddition of dibromobutadiene with trapped propene ions