A promoted PtFe/SiO2 catalyst with low Pt concentration for propane dehydrogenation

Author:

Luo Lei1,Zeng Zekun1,Zhou Tao1,Luo Jun1,Chen Xiaoheng1ORCID,Li Xu12ORCID,Yan Han1ORCID,Zeng Jie13ORCID

Affiliation:

1. Hefei National Research Center for Physical Sciences at the Microscale, CAS Key Laboratory of Strongly-Coupled Quantum Matter Physics, Key Laboratory of Surface and Interface Chemistry and Energy Catalysis of Anhui Higher Education Institutes, Department of Chemical Physics, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China

2. School of Materials and Energy, University of Electronic Science and Technology of China, Chengdu 611731, P. R. China

3. School of Chemistry & Chemical Engineering, Anhui University of Technology, Ma'anshan, Anhui 243002, P. R. China

Abstract

Small PtFe clusters with electron-rich Pt sites show great sintering-resistances and high stability for propane dehydrogenation. The propylene formation rate is 39.52 mol propylene per gram of Pt per hour with 99.9% selectivity for 60 h at a WHSV of 48 h−1.

Funder

National Natural Science Foundation of China

K. C. Wong Education Foundation

National Key Research and Development Program of China

Chinese Academy of Sciences

National Science Fund for Distinguished Young Scholars

Fundamental Research Funds for the Central Universities

Anhui Provincial Key Research and Development Plan

China Association for Science and Technology

Dalian National Laboratory for Clean Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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