Tuning ligand field strength with pendent Lewis acids: access to high spin iron hydrides-Reference-Cited by-同舟云学术

Tuning ligand field strength with pendent Lewis acids: access to high spin iron hydrides

Published:2019 Issue:21 Volume:10 Page:5539-5545
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Kiernicki John J.¹²³⁴,Shanahan James P.¹²³⁴,Zeller Matthias⁵⁶⁷⁴,Szymczak Nathaniel K.¹²³⁴^ORCID

Affiliation:

1. University of Michigan

2. 930 N. University

3. Ann Arbor

4. USA

5. H. C. Brown Laboratory

6. Purdue University

7. West Lafayette

Abstract

Pendent borane Lewis acids provide an avenue for changing a ligand's field strength through acid/base interactions; this strategy was highlighted within a series of biologically-relevant high spin iron hydrides.

Funder

National Institute of General Medical Sciences

Camille and Henry Dreyfus Foundation

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC00561G

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