Extremely active α-olefin polymerization and copolymerization with ethylene catalyzed by a dMAO-activated zirconium(iv) dichloro complex having an [OSSO]-type ligand-Reference-Cited by-同舟云学术

Extremely active α-olefin polymerization and copolymerization with ethylene catalyzed by a dMAO-activated zirconium(iv) dichloro complex having an [OSSO]-type ligand

Published:2015 Issue:108 Volume:5 Page:88826-88831
ISSN:2046-2069
Container-title:RSC Adv.
language:en
Short-container-title:RSC Adv.

Author:

Toda Tomoyuki¹²³⁴,Nakata Norio¹²³⁴,Matsuo Tsukasa⁵⁶⁷¹⁸,Ishii Akihiko¹²³⁴

Affiliation:

1. Department of Chemistry

2. Graduate School of Science and Engineering

3. Saitama University

4. Saitama 338-8570, Japan

5. Functional Elemento-Organic Chemistry Unit

6. RIKEN Advanced Science Institute

7. Wako, Japan

8. Faculty of Science and Engineering

Abstract

We report here the polymerization of α-olefins and copolymerization of ethylene with 1-hexene catalyzed by a zirconium complex incorporating an [OSSO]-type ligand with dried methylaluminoxane (dMAO) as an activator.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA20846G

Reference60 articles.

1. Polymerisation von Äthylen und anderen Olefinen

2. CRYSTALLINE HIGH POLYMERS OF α-OLEFINS

3. Halogen-Free Soluble Ziegler Catalysts for the Polymerization of Ethylene. Control of Molecular Weight by Choice of Temperature

4. Advances in Non-Metallocene Olefin Polymerization Catalysis

Cited by 11 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Isospecific polymerization of sterically bulky α‐olefins catalyzed by zirconium(IV) complex possessing an [OSSO]‐type bis(phenolate) ligand;Journal of Polymer Science;2023-10-20

2. Ethylene homo- and copolymerization catalyzed by vanadium, zirconium, and titanium complexes having potentially tridentate Schiff base ligands;Journal of Catalysis;2021-08

3. [OSSO]-bisphenolate metal complexes: A powerful and versatile tool in polymerization catalysis;Coordination Chemistry Reviews;2021-02

4. Carbazolyl-Substituted [OSSO]-Type Zirconium(IV) Complex as a Precatalyst for the Oligomerization and Polymerization of α-Olefins;Catalysts;2019-06-13

5. Highly Efficient and 1,2-Regioselective Method for the Oligomerization of 1-Hexene Promoted by Zirconium Precatalysts with [OSSO]-Type Bis(phenolate) Ligands;Organometallics;2018-07-27