Spontaneous generation of singlet oxygen on microemulsion-derived manganese oxides with rich oxygen vacancies for efficient aerobic oxidation

Author:

Tang Jun12ORCID,Chen Junbao1,Zhang Zhanyu1,Ma Qincheng1,Hu Xiaolong1,Li Peng1,Liu Zhiqiang1,Cui Peixin3,Wan Chao45,Ke Qingping1,Fu Lei5,Kim Jeonghun6,Hamada Takashi7,Kang Yunqing5,Yamauchi Yusuke678

Affiliation:

1. College of Chemistry and Chemical Engineering, Anhui University of Technology, Maanshan 243002, Anhui, P. R. China

2. School of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006, P. R. China

3. Key Laboratory of Soil Environment and Pollution Remediation, Institute of Soil Science, The Chinese Academy of Sciences, Nanjing 210008, P. R. China

4. College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310058, P. R. China

5. Research Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan

6. Department of Chemical and Biomolecular Engineering, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul 03722, South Korea

7. Department of Materials Process Engineering, Graduate School of Engineering, Nagoya University, Nagoya 464-8603, Japan

8. Australian Institute for Bioengineering and Nanotechnology (AIBN), The University of Queensland, Brisbane, Queensland 4072, Australia

Abstract

We fabricated a range of Ny-MnOx using compartmentalized microemulsion crystallization followed by post-calcination. These materials have the unique ability to generate sufficient 1O2 at room temperature without requiring an external field.

Funder

National Natural Science Foundation of China

Japan Society for the Promotion of Science

Anhui Provincial Department of Education

Natural Science Foundation of Anhui Province

China Postdoctoral Science Foundation

Anhui University of Technology

Exploratory Research for Advanced Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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