An anionic phosphenium complex as an ambident nucleophile-Reference-Cited by-同舟云学术

An anionic phosphenium complex as an ambident nucleophile

Published:2015 Issue:13 Volume:44 Page:6023-6031
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Stadelmann B.¹²³⁴,Bender J.¹²³⁴,Förster D.¹²³⁴,Frey W.⁵²³⁴,Nieger M.⁶⁷⁸⁹¹⁰,Gudat D.¹²³⁴

Affiliation:

1. Institut für Anorganische Chemie

2. Universität Stuttgart

3. 70550 Stuttgart

4. Germany

5. Institut für Organische Chemie

6. Laboratory of Inorganic Chemistry

7. Dept. of Chemistry

8. University of Helsinki

9. 00014 University of Helsinki

10. Finland

Abstract

Treatment of an N-heterocyclic chlorophosphine with Collman's reagent or K[HFe(CO)₄]/NaH gave a unique anionic phosphenium complex which behaves as an ambident nucleophile.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT00008D

Reference51 articles.

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2. M. Sanchez , M. R.Mazières, L.Lamandé and R.Wolf, in Multiple Bonds and Low Coordination Chemistry in Phosphorus Chemistry, ed. M. Regitz and O. J. Scherer, Thieme, Stuttgart, 1990, 129ff

3. Cationic low coordinated phosphorus compounds as ligands: Recent developments

4. Transition Metal Complexes Bearing a Phosphenium Ligand

5. Metal complexes of planar PR2 ligands: Examining the carbene analogy

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