Radical reactions of diamine bis(phenolate) vanadium(iii) complexes. Solid state binding of O2 to form a vanadium(v) peroxo complex-Reference-Cited by-同舟云学术

Radical reactions of diamine bis(phenolate) vanadium(iii) complexes. Solid state binding of O2 to form a vanadium(v) peroxo complex

Published:2017 Issue:29 Volume:46 Page:9692-9704
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Barroso Sónia¹²³⁴⁵^ORCID,Coelho Ana M.¹²³⁴⁵,Adão Pedro¹²³⁴⁵^ORCID,Calhorda Maria José⁶⁷³⁸⁵^ORCID,Martins Ana M.¹²³⁴⁵^ORCID

Affiliation:

1. Centro de Química Estrutural

2. Instituto Superior Técnico

3. Universidade de Lisboa

4. 1049-001 Lisboa

5. Portugal

6. Centro de Química e Bioquímica, DQB

7. Faculdade de Ciências

8. 1749-016 Lisboa

Abstract

Coupling of a V(iii) diamine bis(phenolate) complex with O₂ gives an η²-O₂ complex when the reaction is carried out without a solvent. The latter is an intermediate in the formation of terminal V(v) oxido compounds.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT01699A

Reference84 articles.

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3. Catalytic oxidations by vanadium complexes

4. The Chemistry and Biochemistry of Vanadium and the Biological Activities Exerted by Vanadium Compounds

5. The Bioinorganic Chemistry of Vanadium

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