C–C coupling between trinitrothiophenes and triaminobenzenes: zwitterionic intermediates and new all-conjugated structures-Reference-Cited by-同舟云学术

C–C coupling between trinitrothiophenes and triaminobenzenes: zwitterionic intermediates and new all-conjugated structures

Published:2016 Issue:18 Volume:14 Page:4267-4275
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Boga C.¹²³,Micheletti G.¹²³,Cino S.¹²³,Fazzini S.¹²³,Forlani L.¹²³,Zanna N.¹²³,Spinelli D.⁴⁵³

Affiliation:

1. Department of Industrial Chemistry ‘Toso Montanari’ ALMA MATER STUDIORUM - Università di Bologna Viale del Risorgimento

2. 4 40136 Bologna

3. Italy

4. Department of Chemistry ‘G. Ciamician’ ALMA MATER STUDIORUM - Università di Bologna Via Selmi 2

5. 40126 Bologna

Abstract

An aromatic substitution reaction between trinitrothiophenes andsym-triaminobenzenes: new Wheland–Meisenheimer intermediates, bromo- and nitro-substitution, and unexpected formation of 1-nitroso-2,4,6-triaminobenzenes.

Funder

Università di Bologna

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/OB/C6OB00243A

Reference35 articles.

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4. F. Terrier , Nucleophilic Aromatic Displacement, VCH, New York, 1991

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