d-orbital energy levels in planar [MIIF4]2−, [MII(NH3)4]2+ and [MII(CN)4]2− complexes: the nature of M–L π bonding and the implications for ligand field theory

Author:

Deeth Robert J.1234ORCID

Affiliation:

1. Department of Chemistry

2. University of Warwick

3. Coventry CV4 7AL

4. UK

Abstract

The ‘coordination voids’ above and below the molecular plane exert significant σ and π ligand field effects.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference32 articles.

1. M. T. Weller , T. I.Overton , J. P.Rourke and F. A.Armstrong , Inorganic Chemistry , Oxford University Press , Oxford , 2018

2. M. Gerloch and R. C.Slade , Ligand-Field Parameters , Cambridge University Press , Cambridge , 1973

3. A. B. P. Lever , Inorganic Electronic Spectroscopy , Elsevier , New York , 2nd edn, 1984

4. A. J. Bridgeman and M.Gerloch , in Prog. Inorg. Chem., Vol 45 , ed. K. D. Karlin , 1997 , vol. 45 , pp. 179–281

5. The electronic spectra of tetragonal metal complexes analysis and significance

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