Double allylic defluorinative alkylation of 1,1-bisnucleophiles with (trifluoromethyl)alkenes: construction of all-carbon quaternary centers
Author:
Affiliation:
1. Key Laboratory of Functional Molecular Engineering of Guangdong Province
2. School of Chemistry and Chemical Engineering
3. South China University of Technology
4. Guangzhou 510640
5. China
Abstract
Synthesis of symmetric gem-difluoroalkene substituted products bearing all-carbon quaternary centers via double allylic defluorinative alkylation of 1,1-bisnucleophiles with (trifluoromethyl)alkenes.
Funder
National Basic Research Program of China
National Natural Science Foundation of China
South China University of Technology
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/QO/D0QO00121J
Reference50 articles.
1. Catalytic Enantioselective Desymmetrization Reactions to All-Carbon Quaternary Stereocenters
2. Synthetic Strategies toward Natural Products Containing Contiguous Stereogenic Quaternary Carbon Atoms
3. Fluorine in Pharmaceuticals: Looking Beyond Intuition
4. Fluorine in medicinal chemistry
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