Room temperature olefination of methane with titanium–carbon multiple bonds-Reference-Cited by-同舟云学术

Room temperature olefination of methane with titanium–carbon multiple bonds

Published:2018 Issue:13 Volume:9 Page:3376-3385
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Kurogi Takashi¹²³⁴^ORCID,Won Joonghee¹⁵⁶⁷⁸^ORCID,Park Bohyun¹⁵⁶⁷⁸^ORCID,Trofymchuk Oleksandra S.¹²³⁴,Carroll Patrick J.¹²³⁴,Baik Mu-Hyun¹⁵⁶⁷⁸^ORCID,Mindiola Daniel J.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Pennsylvania

3. Philadelphia

4. USA

5. Korea Advanced Institute of Science and Technology (KAIST)

6. Daejeon 34141

7. Republic of Korea

8. Center for Catalytic Hydrocarbon Functionalizations

Abstract

C–H activation of methane followed by dehydrocoupling at room temperature led ultimately to the formation of the olefin H₂CCH^tBu via the addition of redox-active ligands (L) such as thioxanthone or 2,2′-bipyridine (bipy) to (PNP)TiCH^tBu(CH₃) (1).

Funder

Japan Society for the Promotion of Science

National Science Foundation

University of Pennsylvania

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/SC/C7SC05238C

Reference24 articles.

1. Direct, Nonoxidative Conversion of Methane to Ethylene, Aromatics, and Hydrogen