Impact of air exposure and surface chemistry on Li–Li7La3Zr2O12 interfacial resistance-Reference-Cited by-同舟云学术

Impact of air exposure and surface chemistry on Li–Li7La3Zr2O12 interfacial resistance

Published:2017 Issue:26 Volume:5 Page:13475-13487
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Sharafi Asma¹²³⁴^ORCID,Yu Seungho¹²³⁴^ORCID,Naguib Michael⁵⁶⁷⁴^ORCID,Lee Marcus¹²³⁴,Ma Cheng⁸⁶⁷⁴,Meyer Harry M.⁵⁶⁷⁴,Nanda Jagjit⁵⁶⁷⁴,Chi Maiofang⁸⁶⁷⁴,Siegel Donald J.¹²³⁴^ORCID,Sakamoto Jeff¹²³⁴

Affiliation:

1. Mechanical Engineering Department, Materials Science & Engineering, and Applied Physics Program

2. University of Michigan

3. Ann Arbor

4. USA

5. Materials Science and Technology Division

6. Oak Ridge National Laboratory

7. Oak Ridge

8. Center for Nanophase Materials Sciences

Abstract

Li₇La₃Zr₂O₁₂ (LLZO) reacts with humid air; the most favorable reaction pathway involves protonation of LLZO and formation of Li₂CO₃. The air exposure-induced contamination layer impacts the Li–LLZO interfacial resistance.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/TA/C7TA03162A

Reference44 articles.

1. The rechargeable revolution: A better battery

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4. The Impact of Elastic Deformation on Deposition Kinetics at Lithium/Polymer Interfaces

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