Inquiry for the multifunctional design of metal–organic frameworks: in situ equipping additional open metal sites (OMSs) inducing high CO2 capture/conversion abilities

Author:

Jia Mingwei123,Li Jiantang456,Gu Jiaming123,Zhang Lirong123,Liu Yunling123ORCID

Affiliation:

1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University

2. Changchun 130012

3. P. R. China

4. Functional Materials Design, Discovery & Development (FMD3), Advanced Membranes & Porous Materials Center, Division of Physical Sciences and Engineering, 4700 King Abdullah University of Science and Technology (KAUST)

5. Thuwal 23955-6900

6. Kingdom of Saudi Arabia

Abstract

On the basis of in situ fabricating multifunctional MOFs, a binuclear Co-MOF with open cobalt sites was accomplished. The multifunctional sites afforded increased CO2 uptake, together with the synergistic catalysis in promoting the CO2 conversion.

Funder

Higher Education Discipline Innovation Project

National Natural Science Foundation of China

National Key Research and Development Program of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Materials Science

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