Heterovalent chalcogen bonding: supramolecular assembly driven by the occurrence of a tellurium(ii)⋯Ch(i) (Ch = S, Se, Te) linkage

Author:

Torubaev Yury V.12ORCID,Rozhkov Anton V.3ORCID,Skabitsky Ivan V.1,Gomila Rosa M.4ORCID,Frontera Antonio4ORCID,Kukushkin Vadim Yu.35ORCID

Affiliation:

1. N. S. Kurnakov Institute of General and Inorganic Chemistry of Russian Academy of Sciences, Moscow, 119991, Russian Federation

2. Department of Molecular Chemistry and Materials Science, Weizmann Institute of Science, Rehovot 7610001, Israel

3. Institute of Chemistry, Saint Petersburg State University, Universitetskaya Nab. 7/9, Saint Petersburg, 199034, Russian Federation

4. Department of Chemistry, Universitat de les Illes Balears, 07122 Palma de Mallorca, Baleares, Spain

5. Institute of Chemistry and Pharmaceutical Technologies, Altai State University, 656049 Barnaul, Russian Federation

Abstract

The revealed heterovalent TeII⋯ChI (Ch = S, Se, Te) chalcogen bonding was used for targeted noncovalent integration of two Ch centers in different oxidation states.

Funder

Agencia Estatal de Investigación

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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