Coligand role in the NHC nickel catalyzed C–F bond activation: investigations on the insertion of bis(NHC) nickel into the C–F bond of hexafluorobenzene-Reference-Cited by-同舟云学术

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Coligand role in the NHC nickel catalyzed C–F bond activation: investigations on the insertion of bis(NHC) nickel into the C–F bond of hexafluorobenzene

Published:2020 Issue:40 Volume:11 Page:11009-11023
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Kuntze-Fechner Maximilian W.¹²³⁴,Verplancke Hendrik⁵⁶⁷⁴^ORCID,Tendera Lukas¹²³⁴,Diefenbach Martin⁵⁶⁷⁴,Krummenacher Ivo¹²³⁴⁸,Braunschweig Holger¹²³⁴⁸^ORCID,Marder Todd B.¹²³⁴⁸^ORCID,Holthausen Max C.⁵⁶⁷⁴^ORCID,Radius Udo¹²³⁴^ORCID

Affiliation:

1. Institute for Inorganic Chemistry

2. Julius-Maximilians-Universität Würzburg

3. 97074 Würzburg

4. Germany

5. Institute for Inorganic and Analytical Chemistry

6. Goethe-Universität Frankfurt

7. 60438 Frankfurt

8. Institute for Sustainable Chemistry & Catalysis with Boron

Abstract

A combined experimental and theoretical study on the mechanism of the C–F bond activation of C₆F₆ with [Ni(NHC)₂] is provided.

Funder

Deutsche Forschungsgemeinschaft

Julius-Maximilians-Universität Würzburg

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC04237D

Reference107 articles.

1. Transition-metal fluoro compounds containing carbonyl, phosphine, arsine, and stibine ligands

2. Fluorine chemistry at the millennium

3. K. Uneyama , Organofluorine Chemistry , Wiley-Blackwell , Oxford, U.K. , 2006

4. Fluorine in medicinal chemistry

5. Cross coupling reactions of polyfluoroarenes via C–F activation

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