Homogeneous polymetallic ruthenium(ii)^zinc(ii) complexes: robust catalysts for the efficient hydrogenation of levulinic acid to γ-valerolactone
Author:
Affiliation:
1. Department of Chemistry
2. University of Johannesburg
3. Auckland Park
4. South Africa
Abstract
New Ru(ii) complexes (1 and 2) have been synthesized and reacted with Zn(OAc)2 to form hexanuclear complexes (3 and 4) containing four Ru(ii) and two Zn(ii) centres. The latter are highly active and recyclable catalyst for the conversion of levulinic acid to GVL.
Funder
University of Johannesburg
National Research Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2018/CY/C8CY00265G
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