Sterically demanding methoxy and methyl groups in ruthenium complexes lead to enhanced quantum yields for blue light triggered photodissociation-Reference-Cited by-同舟云学术

Sterically demanding methoxy and methyl groups in ruthenium complexes lead to enhanced quantum yields for blue light triggered photodissociation

Published:2018 Issue:44 Volume:47 Page:15685-15693
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Qu Fengrui¹²³⁴^ORCID,Martinez Kristina⁵⁶⁷⁴^ORCID,Arcidiacono Ashley M.⁵⁸⁹⁴,Park Seungjo¹⁰²³⁴,Zeller Matthias⁵¹¹¹²⁴,Schmehl Russell H.⁵⁶⁷⁴,Paul Jared J.⁵⁸⁹⁴^ORCID,Kim Yonghyun¹⁰²³⁴^ORCID,Papish Elizabeth T.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry & Biochemistry

2. The University of Alabama

3. Tuscaloosa

4. USA

5. Department of Chemistry

6. Tulane University

7. New Orleans

8. Villanova University

9. Villanova

10. Department of Chemical and Biological Engineering

11. Purdue University

12. West Lafayette

Abstract

Ruthenium complexes exhibit enhanced photodissociation quantum yields due to bulky, weak donor ligands, illustrating the impact of electronics and sterics.

Funder

National Science Foundation

University of Alabama

Villanova University

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT03295E

Reference34 articles.

1. Geometry matters: inverse cytotoxic relationship for cis/trans-Ru(ii) polypyridyl complexes from cis/trans-[PtCl2(NH3)2]