All-conjugated donor–acceptor block copolymers featuring a pentafulvenyl-polyisocyanide-acceptor

Author:

Schraff Sandra1234,Maity Sudeshna5678,Schleeper Laura56789,Dong Yifan9101112,Lucas Sebastian1234,Bakulin Artem A.9101112ORCID,von Hauff Elizabeth5678ORCID,Pammer Frank1234ORCID

Affiliation:

1. Institute of Organic Chemistry II and Advanced Materials

2. University of Ulm

3. 89081 Ulm

4. Germany

5. Department of Physics and Astronomy

6. Vrije Universiteit Amsterdam

7. NL-1081 HV Amsterdam

8. Netherlands

9. Department of Chemistry

10. Imperial College London

11. London SW7 2AZ

12. UK

Abstract

A fulvenyl-functionalized polyisocyanide (PIC2) with a high electron mobility of μe = 10−2 cm2 V−1 s−1 has been incorporated into donor–acceptor block copolymers. Their self-assembly and bulk-morphology have been studied, and potential device applications have been explored.

Funder

Verband der Chemischen Industrie

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

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