Pyrene magic: chiroptical enciphering and deciphering 1,3-dioxolane bearing two wirepullings to drive two remote pyrenes

Author:

Amako Tomoyuki12345,Nakabayashi Kazuki12345,Suzuki Nozomu6785,Guo Sibo6785,Rahim Nor Azura Abdul67859,Harada Takunori11011125,Fujiki Michiya6785,Imai Yoshitane12345

Affiliation:

1. Department of Applied Chemistry

2. Faculty of Science and Engineering

3. Kinki University

4. Higashi-Osaka

5. Japan

6. Graduate School of Materials Science

7. Nara Institute of Science and Technology

8. Ikoma

9. School of Materials Engineering

10. Faculty of Engineering

11. Oita University

12. Oita city 870-1192

Abstract

2,2-Dimethyl-1,3-dioxolane connected to two pyrene moieties through flexible wires in chloroform exhibited cryptochirality in the ground state, as proven by the lack of detectable circular dichroism signals.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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