Tetracene cyclophanes showing controlled intramolecular singlet fission by through-space orientations-Reference-Cited by-同舟云学术

Tetracene cyclophanes showing controlled intramolecular singlet fission by through-space orientations

Published:2024 Issue:30 Volume:60 Page:4084-4087
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Sakai Hayato¹^ORCID,Nonaka Keigo²,Hayasaka Ryo¹,Thazhathethil Shakkeeb²,Sagara Yoshimitsu²³^ORCID,Hasobe Taku¹^ORCID

Affiliation:

1. Department of Chemistry, Faculty of Science and Technology, Keio University, Yokohama, Kanagawa 223-8522, Japan

2. Department of Materials Science and Engineering, Tokyo Institute of Technology, Ookayama, Tokyo 152-8522, Japan

3. Living Systems Materialogy (LiSM) Research Group, International Research Frontiers Initiative (IRFI), Tokyo Institute of Technology, 4259 Nagatsuda-cho, Midori-ku, Yokohama, Kanagawa 226-8503, Japan

Abstract

Tetracene cyclophanes: a series of cyclic tetracene dimers bridged by two flexible ethylene glycol units demonstrated enhanced intramolecular singlet fission through through-space orientations by suppressing the H-type excited complex.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC00278D

Reference28 articles.

1. Singlet Fission

2. Triplet Pair States in Singlet Fission

3. Molecular insights and concepts to engineer singlet fission energy conversion devices

4. Mixed Electronic States in Molecular Dimers: Connecting Singlet Fission, Excimer Formation, and Symmetry-Breaking Charge Transfer

5. Molecular Design Strategy for High-Yield and Long-Lived Individual Doubled Triplet Excitons through Intramolecular Singlet Fission