Organometallic Ni(ii), Ni(iii), and Ni(iv) complexes relevant to carbon–carbon and carbon–oxygen bond formation reactions

Author:

Magallón C.1ORCID,Griego L.2,Hu C. H.2,Company A.1ORCID,Ribas X.1ORCID,Mirica L. M.2ORCID

Affiliation:

1. Institut de QuímicaComputacional i Catàlisi (IQCC) and Departament de Química, Universitat de Girona, Campus Montilivi, Girona, E-17003, Catalonia, Spain

2. Department of Chemistry, University of Illinois at Urbana-Champaign, 600 S. Mathews Avenue, Urbana, Illinois 61801, USA

Abstract

Herein, the pyridinophane tetradentate ligand PyNMe3 is used to isolate and structurally characterize well-defined organometallic Ni(ii) and Ni(iii) complexes bearing the cycloneophyl fragment, an alkyl/aryl C-donor ligand.

Funder

National Science Foundation

Ministerio de Economía y Competitividad

Universitat de Girona

Institució Catalana de Recerca i Estudis Avançats

Generalitat de Catalunya

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference54 articles.

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2. J. F.Hartwig , Organotransition Metal Chemistry: From Bonding to Catalysis , University Science Books , Sausalito , 2010

3. Cross-Coupling Reaction of Alkyl Halides with Grignard Reagents Catalyzed by Ni, Pd, or Cu Complexes with π-Carbon Ligand(s)

4. Large-Scale Applications of Transition Metal-Catalyzed Couplings for the Synthesis of Pharmaceuticals

5. Selected Patented Cross-Coupling Reaction Technologies

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