Aldehydes and ketones influence reactivity and selectivity in nickel-catalysed Suzuki–Miyaura reactions
Author:
Affiliation:
1. WestCHEM Department of Pure and Applied Chemistry
2. University of Strathclyde
3. Glasgow
4. UK
5. Syngenta
6. Jealott's Hill International Research Centre
7. Bracknell
Abstract
Aldehydes and ketones can have beneficial or detrimental effects on nickel-catalysed reactions. When present on the aryl halide, excellent site-selectivity can be achieved; when present as additives, they inhibit the reaction.
Funder
Engineering and Physical Sciences Research Council
Carnegie Trust for the Universities of Scotland
University of Strathclyde
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/SC/C9SC05444H
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