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One-step synthesis of benzo[b]thiophenes by aryne reaction with alkynyl sulfides

  • Published:2020 Issue:35 Volume:11 Page:9691-9696
  • ISSN:2041-6520
  • Container-title:Chemical Science
  • language:en
  • Short-container-title:Chem. Sci.

Author:

Matsuzawa Tsubasa12345,Hosoya Takamitsu12345ORCID,Yoshida Suguru12345ORCID

Affiliation:

1. Laboratory of Chemical Bioscience

2. Institute of Biomaterials and Bioengineering

3. Tokyo Medical and Dental University (TMDU)

4. Chiyoda-ku

5. Japan

Abstract

An aryne reaction with alkynyl sulfides affords benzo[b]thiophenes in a one-step simple procedure.

Funder

Japan Society for the Promotion of Science

Naito Foundation

Japan Agency for Medical Research and Development

Core Research for Evolutional Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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1. Chiral stacks of a curved nanographene;Chem;2024-08

2. Bromothiolation of Arynes for the Synthesis of 2-Bromobenzenethiol Equivalents;Organic Letters;2024-04-30

3. 4a Nucleophilic Aromatic Substitution;Organic Reaction Mechanisms Series;2024-03-15

4. Addition Reactions: Cycloaddition;Organic Reaction Mechanisms Series;2024-03-15

5. Sulfonium-based precise alkyl transposition reactions;Science Advances;2023-09-15
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