Does geometry matter? Effect of the ligand position in bimetallic ruthenium polypyridine siblings-Reference-Cited by-同舟云学术

Does geometry matter? Effect of the ligand position in bimetallic ruthenium polypyridine siblings

Published:2020 Issue:13 Volume:49 Page:4125-4135
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Domínguez Sofía E.¹²³⁴⁵^ORCID,Pieslinger German E.¹²³⁴⁵^ORCID,Sanchez-Merlinsky Luciano¹²³⁴⁵,Baraldo Luis M.¹²³⁴⁵^ORCID

Affiliation:

1. Universidad de Buenos Aires

2. Facultad de Ciencias Exactas y Naturales

3. Departamento de Química Inorgánica

4. Buenos Aires

5. Argentina

Abstract

The properties of trans-[Ru^II(tpy)(bpy)(μ-CN)Ru^III(py)₄(L)]^3+/4+ (L = Cl⁻, NCS⁻, DMAP or MeCN) show a transition from localized to delocalized as the ΔE between Ru ions becomes smaller.

Funder

Universidad de Buenos Aires

Consejo Nacional de Investigaciones Científicas y Técnicas

Agencia Nacional de Promoción Científica y Tecnológica

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT00040J

Reference56 articles.

1. Direct approach to measuring the Franck-Condon barrier to electron transfer between metal ions

2. Mixed Valence Chemistry-A Survey and Classification

3. Electronic coupling between metal ions in cyanide-bridged ground state and excited state mixed valence complexes

4. Influence of the Electronic Configuration in the Properties of d6–d5 Mixed-Valence Complexes

5. Exploring the localized to delocalized transition in non-symmetric bimetallic ruthenium polypyridines

Cited by 10 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Cyanido-Bridged Mixed-Valence System: How to Control the Electron Transfer Process;Fundamental Research;2024-03

2. Mixed‐Valence Electron Transfer of Cyanide‐Bridged Multimetallic Systems;Mixed‐Valence Systems;2023-03-10

3. Different delocalized ranges in mixed valence cyanido–metal-bridged Fe–Ru–Fe complexes controlled by terminal ligand substitution modification;Dalton Transactions;2023

4. Influence of the CN Orientation on the Degree of Electron Delocalization of Ru–Ru–Ru Mixed-Valent Complexes;Inorganic Chemistry;2022-10-25

5. Multiple MMCT properties of the diruthenium-based cyanido-bridged complex RuVI2-NC-Ru^II-CN-RuVI2;Dalton Transactions;2022