Boronic ester functionalised 1,8-diboryl-naphthalene scaffolds: fluoride <i>versus</i> oxide chelation-Reference-Cited by-同舟云学术

Boronic ester functionalised 1,8-diboryl-naphthalene scaffolds: fluoride versus oxide chelation

Published:2022 Issue:41 Volume:51 Page:15783-15791
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Booth Anna C.¹^ORCID,Vasko Petra²^ORCID,Fuentes M. Ángeles¹^ORCID,Cornelissen Bart³,Faulkner Stephen¹,Aldridge Simon¹^ORCID

Affiliation:

1. Inorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford, OX1 3QR, UK

2. Department of Chemistry, University of Helsinki, PO Box 55, 00014, Helsinki, Finland

3. Medical Research Council Oxford Institute for Radiation Oncology, Department of Oncology, University of Oxford, Oxford, UK

Abstract

1,8-C10H6(BCat)(BMes2) takes up F− to give a kinetic product featuring a bridging B–F–B unit. An alternative structural motif featuring a terminal B–F bond and a B–O–B bridge using one of the catechol oxygens is shown to be more favourable thermodynamically.

Funder

Engineering and Physical Sciences Research Council

Academy of Finland

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT02888C

Reference49 articles.

1. [18F]-Organotrifluoroborates as Radioprosthetic Groups for PET Imaging: From Design Principles to Preclinical Applications

2. Fluoride Ion Complexation and Sensing Using Organoboron Compounds

3. Synthesis and transport properties of 12-silacrown-3, a new type of anion complexing agent

4. 1,8-Dimethyl-1,8-dihalo-1,8-digermacyclotetradecanes. The first germamacrocycles with anion transport capability

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