Activation of CS2 by a “masked” terminal nickel sulfide-Reference-Cited by-同舟云学术

Activation of CS2 by a “masked” terminal nickel sulfide

Published:2016 Issue:37 Volume:45 Page:14508-14510
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Hartmann Nathaniel J.¹²³⁴,Wu Guang¹²³⁴,Hayton Trevor. W.¹²³⁴

Affiliation:

1. Department of Chemistry and Biochemistry

2. University of California

3. Santa Barbara

4. USA

Abstract

Activation of carbon disulfide (CS₂) by “masked” terminal nickel sulfide, [K(18-crown-6)][(L^tBu)Ni(S)], gives a trithiocarbonate complex. This result confirms the nucleophilicity of the sulfide ligand and expands the scope of reactivity for late metal sulfides.

Funder

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT00885B

Reference30 articles.

1. Oxidative Group Transfer to Co(I) Affords a Terminal Co(III) Imido Complex

2. Intramolecular C?H Activation by an Open-Shell Cobalt(III) Imido Complex

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