Selective iron-catalyzed aerobic oxidation of alcohols in water to carboxylic acids mediated by additives

Author:

Yu Han12ORCID,Ren Jingjing1,Xie Ya1,Su Xiaofang3,Wang Aiping1,Yan Likai3ORCID,Jiang Feng24,Wei Yongge2

Affiliation:

1. School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, P.R. China

2. Key Lab of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, P.R. China

3. Faculty of Chemistry, Northeast Normal University, Changchun, 130024, P.R. China

4. Key Laboratory of Biomaterials and Biofabrication in Tissue Engineering of Jiangxi Province, Gannan Medical University, Ganzhou, Jiangxi 341000, P.R. China

Abstract

The iron catalyst (POM-Fe) could combine with chloride ions to form a supramolecular aggregate FeMo6·Cl, which was used in the oxidation of alcohols to carboxylic acids under mild conditions and can tolerate 40 substrates with moderate to high yield.

Funder

Natural Science Foundation of Jiangxi Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Reference55 articles.

1. Oxidation of Alcohols with Molecular Oxygen on Solid Catalysts

2. Preparative Biotransformations: Oxidation of Alcohols

3. M. A.Ogliaruso and J. F.Wolfe , Synthesis of Carboxylic Acids, Esters and Their Derivatives , in The Chemistry of Functional Groups , ed. S. Patai and Z. Rappoport , John Wiley & Sons , New York , 1991 , pp. 40–49

4. I. W. C. E.Arends and R. A.Sheldon , Modern Oxidation of Alcohols Using Environmentally Benign Oxidants , in Modern Oxidation Methods , ed. J.-E. Bäckvall , Wiley-VCH , Weinheim , 2010 , 2nd edn, pp. 147–185

5. P.Lappe and E.Schulz , Aliphatic Carboxylic Acids via Aldehyde Oxidation , in Applied Homogeneous Catalysis with Organometallic Compounds , ed. B. Cornils and W. A. Herrmann , Wiley-VCH , Weinheim , 1996 , pp. 424–464

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3