Desulfination by 2′-hydroxybiphenyl-2-sulfinate desulfinase proceeds via electrophilic aromatic substitution by the cysteine-27 proton-Reference-Cited by-同舟云学术

Desulfination by 2′-hydroxybiphenyl-2-sulfinate desulfinase proceeds via electrophilic aromatic substitution by the cysteine-27 proton

Published:2017 Issue:7 Volume:8 Page:5078-5086
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Geronimo Inacrist¹²³⁴^ORCID,Nigam Shawn R.¹²³⁴,Payne Christina M.¹²³⁴^ORCID

Affiliation:

1. Department of Chemical and Materials Engineering

2. University of Kentucky

3. Lexington

4. USA

Abstract

Density functional theory shows that the rate-limiting desulfination step in biodesulfurization involves concerted electrophilic substitution with the Cys-27 proton.

Funder

American Chemical Society Petroleum Research Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/SC/C7SC00496F

Reference62 articles.

1. Microbial biocatalyst developments to upgrade fossil fuels

2. Molecular mechanisms of biocatalytic desulfurization of fossil fuels

3. Identification and Cloning of Genes Involved in Specific Desulfurization of Dibenzothiophene by Rhodococcus sp. Strain IGTS8

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