Bioinspired photocatalysed C–H fluoroalkylation of arenes in water promoted by native vitamin B12 and Rose Bengal-Reference-Cited by-同舟云学术

Bioinspired photocatalysed C–H fluoroalkylation of arenes in water promoted by native vitamin B12 and Rose Bengal

Published:2021 Issue:20 Volume:23 Page:8147-8153
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Yerien Damian E.¹,Postigo Al¹^ORCID,Baroncini Massimo²³^ORCID,Barata-Vallejo Sebastián¹⁴^ORCID

Affiliation:

1. Departamento de Ciencias Químicas, Facultad de Farmacia y Bioquímica, Universidad de Buenos Aires, Junín 954, CP 1113, Buenos Aires, Argentina

2. Dipartimento di Scienze e Tecnologie Agro-Alimentari, Università di Bologna, Viale Fanin 44, 40127, Bologna, Italy

3. CLAN-Center for Light Activated Nanostructures, ISOF-CNR, Via P. Gobetti 101, 40129 Bologna, Italy

4. ISOF, Consiglio Nazionale delle Ricerche, Via P. Gobetti 101, 40129, Bologna, Italy

Abstract

Fluoroalkylation of activated arenes was accomplished in water employing the dyad Rose Bengal and unmodified vitamin B12 as photocatalyst and co-catalyst respectively, with fluoroalkyl bromides as radical sources, under green LEDs irradiation.

Funder

Consejo Nacional de Investigaciones Científicas y Técnicas

Secretaria de Ciencia y Tecnica, Universidad de Buenos Aires

Agencia Nacional de Promoción Científica y Tecnológica

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/GC/D1GC02654B

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