N-Hydroxyphthalimide/benzoquinone-catalyzed chlorination of hydrocarbon C–H bond using N-chlorosuccinimide-Reference-Cited by-同舟云学术

N-Hydroxyphthalimide/benzoquinone-catalyzed chlorination of hydrocarbon C–H bond using N-chlorosuccinimide

Published:2019 Issue:13 Volume:17 Page:3403-3408
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Li Zi-Hao¹²³⁴,Fiser Béla⁵⁶⁷⁸⁹,Jiang Biao-Lin¹⁰¹¹¹²¹³¹⁴,Li Jian-Wei¹²³⁴,Xu Bao-Hua¹⁰¹¹¹²¹³¹⁴^ORCID,Zhang Suo-Jiang¹⁰¹¹¹²¹³¹⁴^ORCID

Affiliation:

1. State Key Laboratory of Chemical Resource Engineering

2. Beijing University of Chemical Technology

3. Beijing 100029

4. China

5. Ferenc Rákóczi II. Transcarpathian Hungarian Institute

6. Ukraine

7. Computational Molecular Design Research Group

8. Institute of Chemistry

9. University of Miskolc

10. Beijing Key Laboratory of Ionic Liquids Clean Process

11. Key Laboratory of Green Process and Engineering

12. State Key Laboratory of Multiphase Complex Systems

13. Institute of Process Engineering

14. Chinese Academy of Sciences

Abstract

A metal-free protocol of chlorination of C–H bond with NCS is presented. Both experiments and theoretical analysis suggest NHPI functions as a catalyst rather than an initiator.

Funder

National Natural Science Foundation of China

European Regional Development Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/OB/C9OB00216B

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