Cyclic (amino)(barrelene)carbene Ru-complexes: synthesis and reactivity in olefin metathesis-Reference-Cited by-同舟云学术

Cyclic (amino)(barrelene)carbene Ru-complexes: synthesis and reactivity in olefin metathesis

Published:2024 Issue:12 Volume:53 Page:5346-5350
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Talcik Jakub¹,Serrato Melinda R.²^ORCID,Del Vecchio Antonio¹^ORCID,Colombel-Rouen Sophie¹,Morvan Jennifer¹,Roisnel Thierry¹^ORCID,Jazzar Rodolphe²^ORCID,Melaimi Mohand²,Bertrand Guy²^ORCID,Mauduit Marc¹^ORCID

Affiliation:

1. Univ. Rennes, Ecole Nationale Supérieure de Chimie de Rennes, CNRS, ISCR UMR 6226, F-35000 Rennes, France

2. UCSD-CNRS Joint Research Chemistry Laboratory (IRL 3555), Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, California 92093-0358, USA

Abstract

The first cyclic (amino)(barrelene)carbene (CABC) Ru-complexes were synthesized. They demonstrated remarkable thermal stability at 110 °C and good performance in olefin metathesis.

Funder

Agence Nationale de la Recherche

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT00102H

Reference37 articles.

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5. Intramolecular “Hydroiminiumation” of Alkenes: Application to the Synthesis of Conjugate Acids of Cyclic Alkyl Amino Carbenes (CAACs)

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