H-atom site exchange in an iridium trans-dihydrogen/hydride complex, trans-[Ir(H)(η2-H2)(iPr)4(POCOP)(DMAP)]+-Reference-Cited by-同舟云学术

H-atom site exchange in an iridium trans-dihydrogen/hydride complex, trans-[Ir(H)(η²-H₂)^(iPr)4(POCOP)(DMAP)]⁺

Published:2023 Issue:39 Volume:52 Page:13858-13863
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Agrawal Nisha K.¹,Gayathridevi S.²³,Dash Soumya R.²³,Vanka Kumar²³^ORCID,Jagirdar Balaji R.¹^ORCID

Affiliation:

1. Department of Inorganic & Physical Chemistry, Indian Institute of Science, Bangalore 560 012, India

2. Physical and Materials Chemistry Division, CSIR-National Chemical Laboratory, Pune 411 008, India

3. Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201 002, India

Abstract

Treatment of trans-[Ir(H)(N)2(iPr)4(POCOP)(DMAP)][BAr4f] (2) with H2 (1 bar) under ambient conditions (298 K) results in the formation of a trans-[Ir(H)(η2-H2)(iPr)4(POCOP)(DMAP)][BAr4f] (3) complex. H-atom site exchange between the H2 and the hydride sites takes place in this complex.

Funder

University Grants Commission

Department of Science and Technology, Ministry of Science and Technology, India

Council of Scientific and Industrial Research, India

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT02366D

Reference37 articles.

1. G. J.Kubas , Metal Dihydrogen and σ-Bond Complexes , Kluwer/Plenum , New York , 2001

2. Preparation and spectroscopic properties of the .eta.2-dihydrogen complexes [MH(.eta.2-H2)PR2CH2CH2PR2)2] + (M = iron, ruthenium; R = Ph, Et) and trends in properties down the iron group triad

3. Approaches to Sigma Complexes via Displacement of Agostic Interactions: An Experimental and Theoretical Investigation

4. Heterolytic Activation of H−X (X = H, Si, B, and C) Bonds: An Experimental and Theoretical Investigation

5. Synthesis, Structural Diversity, Dynamics, and Acidity of the M(II) and M(IV) Complexes [MH3(PR3)4]+ (M = Fe, Ru, Os; R = Me, Et)