Strategic enzymatic enantioselective desymmetrization of prochiral cyclohexa-2,5-dienones-Reference-Cited by-同舟云学术

Strategic enzymatic enantioselective desymmetrization of prochiral cyclohexa-2,5-dienones

Published:2024 Issue:52 Volume:60 Page:6647-6650
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Kattula Bhavita¹²^ORCID,Munakala Anandarao³,Kashyap Rajnandani¹,Nallamilli Tarun³²,Nagendla Narendra Kumar⁴²,Naza Surabhi¹²,Mudiam Mohana Krishna Reddy⁴²,Chegondi Rambabu³²^ORCID,Addlagatta Anthony¹²

Affiliation:

1. Department of Applied Biology, Hyderabad, India

2. Academy of Scientific and Innovative Research (AcSIR), Ghaziabad-201002, India

3. Department of Organic Synthesis and Process Chemistry, Hyderabad, Telangana, India

4. Department of Analytical and Structural Chemistry, CSIR-Indian Institute of Chemical Technology, Hyderabad-500 007, Telangana, India

Abstract

Asymmetric desymmetrization through the selective reduction of one double bond of prochiral 2,5-cyclohexadienones is highly challenging.

Funder

Science and Engineering Research Board

University Grants Commission

Department of Science and Technology, Ministry of Science and Technology, India

Council of Scientific and Industrial Research, India

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC02181A

Reference42 articles.

1. Synthesis of β-Alkyl Cyclopentanones in High Enantiomeric Excess via Copper-Catalyzed Asymmetric Conjugate Reduction

2. Conjugate Reduction of α,β-Unsaturated Carbonyl Compounds Catalyzed by a Copper Carbene Complex

3. Asymmetric 1,4-Reductions of Hindered β-Substituted Cycloalkenones Using Catalytic SEGPHOS−Ligated CuH

4. Asymmetric Organocatalytic Reactions of α,β-Unsaturated Cyclic Ketones

5. Enantioselective Synthesis of Tricyclic β-Lactones by NHC-Catalyzed Desymmetrization of Cyclic 1,3-Diketones

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