Photoactivation of triosmium dodecacarbonyl at 400 nm probed with time-resolved X-ray liquidography-Reference-Cited by-同舟云学术

Photoactivation of triosmium dodecacarbonyl at 400 nm probed with time-resolved X-ray liquidography

Published:2022 Issue:53 Volume:58 Page:7380-7383
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Ki Hosung¹²,Kim Tae Wu³^ORCID,Moon Jiwon⁴,Kim Jungmin¹²,Lee Yunbeom¹²,Heo Jun¹²,Kim Kyung Hwan⁵,Kong Qingyu⁶,Khakhulin Dmitry⁷,Newby Gemma⁸,Kim Joonghan⁴^ORCID,Kim Jeongho⁹^ORCID,Wulff Michael⁸,Ihee Hyotcherl¹²^ORCID

Affiliation:

1. Center for Advanced Reaction Dynamics, Institute for Basic Science (IBS), Daejeon 34141, Republic of Korea

2. Department of Chemistry and KI for the BioCentury, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Republic of Korea

3. Department of Chemistry, Mokpo National University, Muan-gun, Jeollanam-do 58554, Republic of Korea

4. Department of Chemistry, The Catholic University of Korea, Bucheon 14662, Republic of Korea

5. Department of Chemistry, Pohang University of Science and Technology (POSTECH), Pohang 37673, Republic of Korea

6. Synchrotron Soleil, L’Orme des Merisiers, Saint-Aubin, BP 48, 91192 Gif-sur-Yvette Cedex, France

7. European XFEL, Holzkoppel 4, 22869 Schenefeld, Germany

8. European Synchrotron Radiation Facility, BP 220, 38043 Grenoble Cedex, France

9. Department of Chemistry, Inha University, Incheon 22212, Republic of Korea

Abstract

Photoactivation mechanism of triosmium dodecacarbonyl is elucidated via time-resolved X-ray liquidography, identifying two pathways, vibrational relaxation and ligand dissociation.

Funder

Institute for Basic Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC02438A

Reference31 articles.

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3. Photochemical reactivity of Os3(CO)12 and thermal activation of diosmacyclobutanes towards alkynes

4. R. G.Austin , R. S.Paonessa , P. J.Giordano and M. S.Wrighton , in Inorganic and Organometallic Photochemistry , American Chemical Society , Washington , 1978 , pp. 189–214 10.1021/ba-1978-0168.ch012

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