Structural evolution from preorganized mononuclear triazamacrocyclic metalloligands to polynuclear metallocages and heterometallic 2D layers: modular architectures, assembly tracking and magnetic properties

Abstract

The modular assembly of aesthetically fascinating polynuclear metallocages and 2D heterometallic coordination networks was achieved from preorganized azamacrocyclic metalloligands through precisely regulating the reaction parameters.